The Environmental Working Group says that the following fruits and vegetables are very unlikely to have been contaminated by chemicals -- so don't waste your money buying "organic" these.
Onions,
Sweet corn
Pineapple
Avocado
Asparagus
Sweet peas
Mangos
Egg plant
Cantaloupe
Kiwi
Cabbage
Watermelon
Sweet potatoes (which you would have to dig up to spray)
Grapefruit
Mushrooms.
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